Shimadzu LCMS-8045 CL Benutzerhandbuch Seite 141

### Sample Information ###
Sample Type: PEG+PPG+Raffinose
### Tuning Condition ###
Detector Adjustment: On
Resolution Adjustment: On
FWHM of Spectrum: 0.70
Sensitivity Adjustment: On
Mass Calibration: On
### Tuning Result ###
Model: LCMS-8045
Interface: DUIS
Polarity: Pos
Tuning Mode: Auto
Tuning Date: 5/17/2017 11:06:01 AM
Acquisition Mode: Q3 Scan(Use CID Gas)
Nebulizing Gas Flow: 1.50(settings : 1.50) L/min
Drying Gas Flow: 0.00(settings : 10.00) L/min
### Tuning Profile ###
CD:-10.00 kV CD:-10.00 kV CD:-10.00 kV
Int.: 13933257 Int.: 894757
FWHM: 0.73 FWHM: 0.70
m/z : 45.05 m/z : 168.10
Mag.: 1 Mag.: 22
Scan Range: 2.00 - 2000.00 Scan Speed: 30 u/s Base Peak: 445.35 (20000000)
100
300.20
256.15
168.10
100 300 500
m/z(Target) m/z(Actual) Difference
45.05 45.10 0.05
168.10 168.10 0.00
256.15 256.15 0.00
300.20 300.20 0.00
652.40 652.40 0.00
1004.60 1004.60 0.00
1224.75 1224.80 0.05
1603.15 1603.25 0.10
Const 65.05
DL Bias Const +0.0 +0.0
Qarray Bias Const +0.0 +0.0
Qarray RF Scan +50.0 +19.3
Multipole RF Scan +100.0 +30.0
Multipole1 Bias Const +0.0 +0.0
Multipole1 Lens Const -0.8
Multipole2 Bias Const -0.8
Multipole2 Lens Const -1.0
Q1 Bias Const -3.5
CC Lens1 Const +0.0 +0.0
CC Lens2 Const -100.0 -100.0
CC Lens3 Const -20.0 -20.0
Const 65.05
CC RF Scan +200.0 +70.0
CE Scan -5.0
Q3 Bias Scan -7.0
Const 107.15 1071.50 1893.40
Q1 Pre Bias Scan -15.0
Q3 Pre Bias Scan -15.0
CID Gas Flow:
Heating Gas Flow:
Interface Bias:
Interface Current:
Interface Temp.:
DL Temp.:
Heat Block Temp.:
Q1 RF Gain:
Q1 RF Offset:
Q3 RF Gain:
Q3 RF Offset:
Q1 Post-rod Bias:
CID CELL Exit Lens:
Conversion Dynode:
Detector:
PG Vacuum:
IG Vacuum:
Corona Needle Voltage:
Corona Needle Current:
CD:-10.00 kV CD:-5.00 kV
Int.: 3389768 Int.: 5513393 Int.: 3729706
FWHM: 0.67 FWHM: 0.67 FWHM: 0.67
m/z : 256.15 m/z : 300.20 m/z : 652.40
Mag.: 5 Mag.: 3
828.50
1004.60
652.40
700 900 1100
Width Intensity
0.73 13933257
0.70 894757
0.67 3389768
0.67 5513393
0.67 3729706
0.68 4922501
0.70 1949180
0.70 236558
168.10 256.15 344.20 652.40 1004.60 1893.40
+0.0 +0.0 +0.0 +0.0
+0.0 +0.0 +0.0 +0.0
+50.0 +90.0 +90.0 +130.0
+50.0 +50.0 +50.0 +300.0
+0.0 +0.0 +0.0 +0.0
-0.8 -0.8 -0.8 -0.8 -0.8
-0.8 -0.8 -0.8 -0.8 -0.8
-1.0 -1.0 -1.0 -1.0 -1.0
-3.5 -3.5 -3.5 -3.5 -3.5
+0.0 +0.0 +0.0 +0.0
-100.0 -100.0 -100.0 -100.0
-20.0 -20.0 -20.0 -20.0
168.10 256.15 344.20 652.40 1004.60 1893.40
+110.0 +130.0 +300.0 +300.0
-5.0 -5.0 -5.0 -5.0 -5.0
-7.0 -7.0 -7.1 -7.2 -7.6
-5.0 -50.0 -50.0
-5.0 -50.0 -50.0
230(settings : 230) kPa
4.97(settings : 5.00) L/Min
+4.00 kV
0.90 uA
100(settings : 100) C
250(settings : 250) C
400(settings : 400) C
---
---
4998
5000
-5.0 V
-4.0 V
-10.00 kV
-2.28(-2.28) kV
7.2e+001 Pa
2.1e-003 Pa
+4.50 kV
0.10 uA
CD:-5.00 kV CD:-10.00 kV
Int.: 4922501 Int.: 1949180
FWHM: 0.68 FWHM: 0.70
m/z : 1004.60 m/z : 1224.75
Mag.: 5 Mag.: 4 Mag.: 10
1224.80 1312.80
1603.25
1300 1500 1700
+0.0 +0.0
+0.0 +0.0
+130.0 +130.0
+300.0 +300.0
+0.0 +0.0
-0.8 -0.8
-0.8 -0.8
-1.0 -1.0
-3.5 -3.5
+0.0 +0.0
-100.0 -100.0
-20.0 -20.0
+300.0 +300.0
-5.0 -5.0
-8.0 -9.0
LCMS-8045
3.8 Auto-Tuning
CD:-10.00 kV
3
Int.: 236558
FWHM: 0.70
m/z : 1603.15
Mag.: 83
1893.50
1900
97
LCMS-8050
CL CL